LITHIUM POLYMER BATTERY
UL2054
1.1 These requirements cover portable primary (non-rechargeable) and secondary (rechargeable) lithium polymer batteries for use as power sources in products. These lithium polymer batteries consist of either a single electrochemical cell or two or more cells connected in series, parallel, or both, that convert chemical energy into electrical energy by chemical reaction. 1.2 These requirements are intended to reduce the risk of fire or explosion when lithium polymer batteries are used in a product. The proper use of these lithium polymer batteries in a particular application is dependent on their use in a complete product that complies with the requirements applicable to such a product. 1.3 These requirements are intended to cover lithium polymer batteries for general use and do not include the combination of the battery and the host product which are covered by requirements in the host product standard. 1.4 These requirements are also intended to reduce the risk of injury to persons due to fire or explosion when batteries are removed from a product to be transported, stored, or discarded. 1.5 These requirements do not cover the toxicity risk that results from the ingestion of a lithium polymer battery or its contents, nor the risk of injury to persons that occurs if a lithium polymer battery is cut open to provide access to its contents.
UL2054: lithium polymer battery
2.1.1 In lieu of the requirements outlined in Table 6.1 cells constructed of lithium metal, lithium alloy or lithium-ion, that are used in batteries, shall meet the requirements in the Standard for Lithium Polymer Batteries, UL 1642.
2.2 Units of measurement
2.3 Terminology
2.4 Components
2.4.1 Except as indicated in 2.4.2, a component of a product covered by this standard shall comply with the requirements for the component. See Appendix A for a list of standards covering components used in the products covered by this standard.
2.4.2 A component is not required to comply with a specific requirement that:
a) Involves a feature or characteristic not required in the application of the component in the product covered by this standard, or b) Is superseded by a requirement in this standard.
2.4.3 A component shall be used in accordance with its rating established for the intended conditions of use.
2.4.4 Specific components are incomplete in construction features or restricted in performance capabilities. Such components are intended for use only under limited conditions, such as certain temperatures not exceeding specified limits, and shall be used only under those specific conditions.
Lithium Polymer Battery UL2054 Construction
Casing
4.1.1 The casing of a cell or single-cell lithium polymer battery, or the enclosure of a lithium polymer battery pack shall have the strength and rigidity required to resist the possible abuses, that it is exposed to during its intended use, in order to reduce the risk of fire or injury to persons.
4.1.2 The casing of a lithium polymer battery pack shall be rigid enough to prevent flexing. A tool providing the mechanical advantage of pliers, screwdriver, hacksaw, or similar device, shall be the minimum automatic capability required to open the casing.
4.1.3 For lithium polymer battery packs with plastic outer enclosures, the external ring of the lithium polymer battery shall be designed such that it is not capable of being opened using simple tools, such as a screwdriver. The enclosure shall be ultrasonically welded or secured by equivalent means. Adhesives complying with the adhesive requirements of the Standard for Polymeric Materials – Use in Electrical Equipment Evaluations, UL 746C, single-use, or tamper-proof screws are considered equivalent means.
4.1.4 The outer case material of the lithium polymer battery shall be classed as V-1 or less flammable in the minimum part thickness following the Standard for Polymeric Materials — Use in Electrical Equipment Evaluations, UL 746C.
Exception: Materials are not required to be classed as V-1 or less flammable when they comply with the Enclosure Flammability – 20 mm (3/4 inch) Flame test described in the Standard for Polymeric Materials– Use in Electrical Equipment Evaluations, UL 746C.
4.1.5 Openings in lithium polymer battery pack enclosures shall be minimized to prevent damage to cells, connections, and internal circuitry and too short of electrical spacings within the pack. Enclosure openings shall not be located over cells that do not comply with the rigid casing requirements of 4.1.2 or overprotective circuitry and connections where damage or shorting from debris entering the enclosure could result in a hazard.
Electrolyte
4.2.1 A lithium polymer cell shall not contain pressurized vapor or liquid that expels materials forcibly when the lithium polymer battery casing is punctured with a grinding wheel under laboratory conditions at a temperature of 23 ±2°C (73±3.6°F).
External battery pack connectors
4.3.1 An external lithium polymer battery pack connector shall be constructed to prevent inadvertent short-circuiting of its terminals unless the pack meets the limited power source requirements of the Limited Power Source Test, Section 13. Examples of methods to prevent inadvertent short-circuiting include recessing the terminals, providing circuitry that prevents inadvertent short-circuiting, providing covers over the terminals, use of keyed connectors, and the like.
4.3.2 Insulating material for external lithium polymer battery pack connectors, outside the enclosure, shall have a V-2 minimum flame rating unless the pack meets the limited power source requirements of the Limited Power Source Test, Section 13. External connectors forming part of the fire enclosure shall be V-1 minimum.
Printed wiring boards
4.3.1 An external lithium polymer battery pack connector shall be constructed to prevent inadvertent short-circuiting of its terminals unless the pack meets the limited power source requirements of the Limited Power Source Test, Section 13. Examples of methods to prevent inadvertent short-circuiting include recessing the terminals, providing circuitry that prevents inadvertent short-circuiting, providing covers over the terminals, use of keyed connectors, and the like.
4.3.2 Insulating material for external lithium polymer battery pack connectors, outside the enclosure, shall have a V-2 minimum flame rating unless the pack meets the limited power source requirements of the Limited Power Source Test, Section 13. External connectors forming part of the fire enclosure shall be V-1 minimum.
Lithium ion systems only
4.5.1 The voltage of each cell or each cellblock consisting of parallel-connected plural cells should not exceed the upper limit of the charging voltage specified by the cell manufacturer.
4.5.2 For the lithium polymer battery consisting of a single cell or a separate cellblock, it should be confirmed that the charging voltage of the cell does not exceed the upper limit of the charging voltage specified by the cell manufacturer
4.5.3 For the lithium polymer battery consisting of series-connected plural single cells or series-connected plural cellblocks, it should be confirmed that the energies of any one of the individual cells or single cellblocks does not exceed the upper limit of the charging voltage, specified by the cell manufacturer, by monitoring the energy of every single cell or the single cellblocks.
4.5.4 Compliance for 4.5.1 – 4.5.3 can be achieved through analysis of the lithium polymer battery protection circuit or if unable to determine through analysis, then through monitoring values during the test of Section 13A.
Lithium Polymer Battery UL2054 Performance
General
5.1 Lithium Polymer Batteries are to be tested as described in Sections 9 through 24. Section 12, Forced-Discharge Test, is applicable only to cells intended to be used in multicell series applications, such as battery packs. The lithium polymer Battery Enclosure Tests, Sections 18 — 21
(including the 250 N Steady Force, Mold Stress Relief, and Drop Impact Tests) are intended only for batteries that have a plastic outer enclosure.
5.2 With the exception of the Projectile Test of Section 22, cells and/or batteries shall not explode or catch fire as a result of the tests in this standard. For the Shock Test, Section 16, Vibration Test, Section 17, 250 N Steady Force Test, Section 19, Mold Stress Relief Test, Section 20, Drop Impact Test, Section 21, and the Temperature Cycling Test, Section 24 the samples shall also not vent or leak. For these tests unacceptable leakage is deemed to have occurred when the resulting mass loss exceeds the values shown in Table 5.1, Venting and Leakage Mass Loss Criteria.
5.3 Deleted August 12, 2008
5.4 Certain end product devices require that the power output of a lithium polymer battery be limited. The Limited Power Source Test described in Section 13 is to be used to determine whether a cell or battery is suitable in such applications where fire hazards may otherwise exist.
Samples
6.1 Unless otherwise indicated, new lithium polymer cells or batteries in the fully charged state are to be used for the tests described in Sections 9 – 24. The test program and a number of samples to be used in each analysis are shown in Tables 6.1 and 6.2, for cell testing and battery pack testing, respectively.
6.2 When a lithium polymer battery pack is tested in accordance with Table 6.2, the cells comprising that battery pack shall also be tested in accordance with Table 6.1 if they have not already been.
6.3 All lithium polymer batteries shall be fully charged in accordance with the manufacturer’s specifications prior to testing except for the samples to be subjected to the Abnormal Charging and Abusive Overcharge Tests, which shall be discharged to the manufacturer specified endpoint voltage using the manufacturer specified current prior to testing.
Important test considerations
7.1 As some lithium polymer batteries explode in the tests described in Sections 9 — 24, it is important that personnel be protected from the flying fragments, explosive force, sudden release of heat, chemical bums, and noise results from such explosions. The test area is to be well ventilated to protect personnel from possible harmful fumes or gases.
7.2 The temperatures on the surface of the battery casings shall be monitored during the tests described in Sections 9, 10, 11, 14, and 15. All personnel involved in the testing of lithium polymer batteries are to be instructed never to approach a lithium polymer battery until the surface temperature returns to ambient temperature.
7.3 The tests described in Section 22, Projectile Test, shall be conducted in a separate room or room equipped with an adequate safety barrier separating the test area from the observer.
Temperature measurements
8.1 Temperatures are to be measured by thermocouples consisting of wires not larger than 24 AWG (0.21 mm2) and not smaller than 30 AWG (0.05 mm2) and a potentiometer-type instrument.
8.2 The temperature measurements on the lithium polymer batteries are to be made with the measuring junction of the thermocouple held tightly against the outer casing of the lithium polymer battery.
Lithium Polymer Battery UL2054 Electrical Tests
Short-Circuit Test
9.1 Cells shall comply with 9.1 — 9.6.
(Underwriter Laboratories Inc. approved battery cell used in the EUT according to UL1642)
9.2 Each fully charged test sample cell, in turn, is to be short-circuited by connecting the positive and negative terminals of the lithium polymer battery with a circuit load having a resistance load of 80 ± 20 moms. The temperature of the battery case is to be recorded during the test. The lithium polymer battery is to discharge until a fire or explosion is obtained, or until it has reached an unloaded state of fewer than 0.2 volts and the case temperature has returned to ±10°C (±18°F) of ambient temperature.
9.3 Tests are to be conducted at 20 ± 5°C (68 ± 9°F), and at 55 ± 2°C (131 ± 4°F). The cells are to reach equilibrium at 20 ± 5°C (68 ± 9°F) or 55 ± 2°C (131 ± 4°F) as applicable, before the terminals are connected.
9.4 A lithium polymer cell is to be tested individually unless the cell manufacturer indicates that it is intended for use in series or parallel. For series or parallel use, additional tests on five sets of lithium polymer batteries are to be conducted using the maximum number of cells to be covered for each configuration as specified by the manufacturer.
9.5 A lipo cell is to be tested without the assistance of protective devices unless such protective mechanisms are integral to the lipo cell construction. When protective equipment actuates during the test, the test shall be repeated with the lipo cell connected to the maximum load that does not cause the protective device to open.
9.6 The samples shall not explode or catch fire. The temperature of the exterior cell or lithium polymer battery casing shall not exceed 150°C (302°F) for lithium chemistries. °C
9.7 Lithium Polymer Battery packs shall comply with 9.8 —9.12.
Exception: Lithium Polymer Battery packs consisting of a single cell, in which the cell has already been subjected to the tests in 9.1 – 9.6 need not be submitted to the criteria in 9.8 – 9.12
9.8 Each fully charged test sample lithium polymer battery pack, in turn, is to be short-circuited by connecting the positive and negative terminals of the lithium polymer battery with a circuit load having a resistance load of 80 ± 20 m ohm. The temperature of the lithium polymer battery case is to be recorded during the test. The lithium polymer battery is to discharge until a fire or explosion is obtained, or until it is ultimately released and the cell case temperature has returned to ±10°C (±18°F) of ambient temperature.
9.9 Tests are to be conducted at 20 ± 5°C (68 ± 9°F) and 55 ± 5°C (131 ± 4°F). The lithium polymer batteries are to reach equilibrium at 20 ± 5°C (68 ± 9°F) or 55 ± 5°C (131 ± 4°F), as applicable, before the terminals are connected.
9.10 Lithium Polymer Battery pack constructions are to be subjected to a single fault across any protective device in the load circuit of the lithium polymer battery under test. When protective devices actuate during the trial, the examination shall be repeated with the lithium polymer battery pack connected to the maximum load that does not cause the protective devices to open.
Exception: A positive temperature coefficient device which complies with the tests specified in Standard for Thermistor-Type Devices, UL 1434, the Standard for Automatic Electrical Controls for Household and Similar Use, Part 1: General Requirements, UL 60730-1A, or other protective devices determined to be reliable, may remain in the circuit without being faulted. See Appendix A for additional component standards.
9.11 One of the above five test sample lithium polymer battery packs, tested at 20 ±5°C (68 ±9°F) shall be evaluated with the following additional conditions in place. The terminals are to be subjected to a short circuit condition with a minimum length of 16 AWG (1.3 mm2) bare copper wire. The test is to be conducted on a tissue paper covered softwood surface, and the sample lithium polymer battery pack and bare conductor is to be covered with a single layer of cheesecloth.
9.12 For all samples tested, the samples shall not explode or catch fire, and the tests shall not result in chemical leaks caused by cracking, rupturing, or bursting of the cell casing. The temperature of the internal cell casings shall not exceed 150°C (302°F) for lithium chemistries. For battery pack samples tested following 9.11, the cheesecloth and tissue paper shall not catch fire.
Abnormal Charging Test
10.1 Primary lithium polymer batteries (for example lipo cells, single lipo cell batteries, or lipo battery packs) shall comply with 10.2 –10.5
(Secondary battery pack)
10.2 Lithium Polymer Batteries discharged to the manufacturer’s rated capacity are to be used for this test. The lithium polymer batteries are to be tested in an ambient temperature of 20 ± 5°C (68 ± 9°F).
10.3 Each fully discharged test sample battery is to be subjected to a charging current of three times the current lc, specified by the manufacturer by connecting it in opposition to a dc-power supply.
The test time is to be calculated using the formula:
in which
it is the charging time in an hour
C is the capacity of the lipo cell /lithium polymer battery in ampere-hours,
and lc is the maximum charging current, in amperes, specified by the manufacturer.
The minimum charging time is to be 7 hours.
Exception: At the manufacturer’s discretion, test currents greater than the specified three times rated Ic can be applied to expedite the test timeframe, with the minimum charging times as 7 hours.
10.4 When a protective device that has been investigated for the purpose, actuates during the test, the test shall be repeated with the battery supply connected to the maximum load that does not cause the protective device to open. A protective device that has not been investigated for the purpose shall be short-circuited.
10.5 The samples shall not explode or catch fire. For battery pack samples, tests shall not result in chemical leaks caused by cracking, rupturing or bursting of the battery casing.
10.6 Secondary cells shall comply with 10.7 – 10.9 (Underwriter Laboratories Inc. approved battery cell used in the EUT according to UL1642)
10.7 The cells are to be tested in an ambient temperature of 20 ± 5°C (68 ± 9°F). Each lithium polymer battery shall be discharged at a constant current of 0.2 C/1 hours, to a manufacturer specified discharge endpoint voltage
10.8 The cells are to be charged with a constant maximum specified charger output voltage and a current limit of three times the maximum current Ic, specified by the manufacturer. Charging duration is the time required to reach the manufacturer’s specified end-of-charge condition plus seven additional hours.
10.9 A cell is to be tested without the assistance of protective devices unless such protective devices are either integral to the cell constructions or have been investigated for the purpose. A re-settable protective device that actuates during the test shall be allowed to reset and the test shall be resumed, cycling as often as necessary to complete the test. When a protective device operates during the test (whether re-settable or not) the test is repeated with the same charging time, but with the cell connected to the maximum load that does not cause the protective devices to operate. A protective device that is not integral to the cell and that has not been investigated for the purpose is to be short-circuited.
10.10 Secondary battery packs shall comply with 10.11 — 10.13.
10.11 The lithium polymer batteries are to be tested in an ambient temperature of 20±5°C (68±9°F). A thermocouple is to be attached to the cells of each test sample battery. Each lithium polymer battery shall be discharged at a constant current of 0.2C/1 hour, to a manufacturer specified discharge endpoint voltage.
10.12 Each of the test sample lithium polymer batteries are to be subjected to the following overcharge conditions, in sequential order. a) The battery is to be initially charged using a constant current charging mode with a current limit of three times the maximum current Ic, specified by the manufacturer until the maximum specified charger output voltage is reached. At that point, the lithium polymer battery is to be charged with a constant maximum specified charger output voltage and a current limit of three times the maximum current Ic. Charging duration is the time required to reach the manufacturer’s specified end-of-charge condition plus seven additional hours. The temperature on the cell casing shall be monitored. A re-settable protective device such as a PTC that actuates during the test shall be allowed to reset and the test shall be resumed, cycling as often as necessary, but no less than 10 times, to complete the test. Automatic reset devices are allowed to cycle during the test. When an overcurrent protective device operates during the test, the test is repeated with the same charging time, but with the lithium polymer battery connected to the maximum load that does not cause the protective devices to operate. b) The charge condition in accordance with (a) shall be conducted with each single component fault that is likely to occur in the charging circuit and which would result in overcharging of the battery. Exception No. 1: A protective device determined to be reliable may remain in the circuit without being faulted. See 2.4 and Appendix A. Exception No. 2: For lithium polymer batteries without protective devices, the overcharge condition(s) in (b) does not apply.
10.13 The samples shall not explode or catch fire. For lithium polymer battery pack samples, tests shall not result in chemical leaks caused by cracking, rupturing or bursting of the internal cell casing.
Abusive Overcharge Test (Underwriter Laboratories Inc. approved lithium polymer battery cell used in the EUT according to UL1642)
11.1 The lithium polymer batteries are to be tested in an ambient temperature of 20 ±5°C (68 ±9°F).
11.2 Sample lithium polymer batteries are to be subjected to a constant charging current at ten times the C5 amp rate, using a supply voltage sufficient to maintain the ten times C5 amp rate throughout the test. During the trial, the temperature is to be measured on the internal cell casing of each sample. The test is to continue until the cell or battery explodes, vents, or a single operation protective device operates, and the temperature of the internal cell casing reaches steady-state conditions or returns to ambient. If a PTC or other re-settable protection device works during the test, it is to be reset a minimum of 10 times during the trial. An automatic reset device is allowed to cycle during the test
11.3 During the tests, lithium polymer batteries supplied with protective devices shall be subjected to a single component fault using any individual fault condition which is likely to occur in the charging circuit and which would result in overcharging of the battery Exception: Protective devices determined to be reliable, may remain in the loop without being faulted. See Appendix A.
11.4 The samples shall not explode or catch fire.
11.5 At least one of the five samples shall be subjected to the test outlined in 11.2 and 11.3 with a constant current charge five times the C5 rate (for example: at the C rate) with a supply voltage sufficient to maintain that rate throughout the test
Forced-Discharge Test
12.1 This test is intended for cells that are to be used in multicell applications, such as lithium polymer battery packs. The batteries are to be tested in an ambient temperature of 20 ±5°C (68 ±9°F).
12.2 For multi-cell series configurations without parallel strings a fully discharged cell is to be force-discharged by connecting it in series with fully charged cells of the same kind. The number of fully charged cells to be connected in series with the discharged cell is to equal the total number of cells in the pack less one.
12.3 For multi-cell series configurations with parallel strings, a fully discharged parallel string is to be force-discharged by connecting it in series with fully charged cells of the same kind. The number of fully charged cells to be connected in series with the discharged parallel string is to equal the total number of cells in the pack less the number of cells in the discharged parallel string.
12.4 Each of the five lithium polymer battery packs shall be prepared as described in 12.2 or 12.3, as applicable.
12.5 Once the completely discharged cells (or string of cells) are connected in series with the specified number of fully charged cells, the resultant battery pack is to be short-circuited.
12.6 The positive and negative terminals of the sample are to be connected with copper wire with a resistance load of 80 ± 20 m ohms. The battery is to discharge until a fire or explosion is obtained, or until it has reached a completely discharged state and the cell case temperature has returned to ±10°C
(±18°F) of ambient temperature.
12.7 During the tests, lithium polymer batteries supplied with protective devices shall be subjected to a single component fault using any single fault condition which is likely to occur in the discharge circuit and which would result in excessive discharge of the lithium polymer battery.
Exception: A positive temperature coefficient device which complies with the applicable tests specified in the Standard for Thermistor-Type Devices, UL 1434 and the Standard for Automatic Electrical Controls for Household and Similar Use, Part 1: General Requirements, UL 60730-1A, or other protective devices determined to be reliable, may remain in the circuit without being faulted. See Appendix A for additional component standards.
12.8 The samples shall not explode or catch fire.
Limited Power Source Test (Not applied)
13.1 The lithium polymer batteries are to be tested in an ambient temperature of 20 ±5°C (68 ±9°F).
13.2 A lithium polymer battery intended to be a limited power source shall comply with one of the following:
a) The output is inherently limited in compliance with Table 13.1; or
b) A linear or nonlinear impedance limits the output in compliance with Table 13.1. If a positive temperature coefficient device is used, it shall:
1) Comply with the Standard for Thermistor-Type Devices, UL 1434, or
2) Pass the tests specified in the Manufacturing Deviation and Drift Section, the Endurance Section, and the Manufacturing Deviation and Drift Section and the Endurance Section in the Annex for Requirements for Controls Using Thermistors of the Standard for Automatic Electrical Controls for Household and Similar Use, Part 1: General Requirements, UL 60730-1; or
3) Meet the requirements in the Standard for Automatic Electrical Controls for
Household and Similar Use, Part 1: General Requirements, UL 60730-1 for a device for
Type 2.AL Action;
c) A regulating network or an integrated circuit (IC) current limiter, limits the output in compliance with Table 13.1, both under normal operating conditions and after any simulated single fault in the regulating network or IC current limiter (open circuit or short circuit); or
d) An overcurrent protective device is used and the output is limited in compliance with Table 13.2.
13.3 Where an overcurrent protective device is used, it shall be a fuse or a non-adjustable, no auto-reset, electromechanical device.
13.4 Lithium Polymer Batteries shall be fully charged when conducting the measurements for Uoc ISC, and S according to Tables 13.1 and 13.2.
13.5 The non-capacitive load referenced in Tables 13.1 and 13.2 shall be adjusted to develop maximum measured values of current (Isc) and power (S) that can be obtained over the time limits noted in Tables 13.1 and 13.2. Simulated faults in a regulating network required according to 13.2 item (c) above are applied under these load conditions.
Lithium Polymer Batteries that meet the limited power source requirements may be marked “Limited Power Source” “LPS” to indicate that they are considered to be a limited power source. Lithium Polymer Batteries that do not meet these requirements, regardless of terminal design, shall not be marked to indicate that they are a limited power source and are restricted to applications where a limited power source is not required
13A Lithium Polymer Battery Pack Component Temperature Test
13A.1 A lithium polymer battery pack with enclosure shall be subjected to a normal temperature test under both input (charging) and output (discharging) conditions. As a result of this testing, temperatures on temperature-sensitive components shall not exceed the limits outlined in Table 13A.1
13A.2 For the output loading temperature test, a fully charged lithium polymer battery pack shall be subjected to a constant resistive loading across the output terminals of the pack with the output load current set to just below the operating limit of the discharging protection circuit. Temperatures are monitored until thermal stabilization or until the pack is at its specified endpoint voltage, whichever comes first.
13A.3 The input loading temperature test shall be conducted on a fully discharged lithium polymer battery pack, discharged at a constant current of 0.2C/1 hour to a manufacturer specified discharge endpoint voltage.
13A.4 For the input loading temperature test, a fully discharged sample shall be subjected to a CCCV charging method with the maximum charging voltage not to exceed the manufacturer’s recommended maximum charging voltage limits. During the test, the charging current shall not exceed three times the maximum charge current or the operating limit of the charging protection circuit, whichever is less, during the test. Temperatures are monitored until thermal stabilization or until the pack is at its fully charged state, whichever comes first.
13A.5 Temperatures are considered to be stabilized when three successive readings are taken at intervals of 10 percent of the previously elapsed duration of the test, but not less than 15 minutes, indicate no further increase.
13A.6 Protective devices within the pack shall not operate during the test.
13A.7 Temperatures are monitored on surfaces of components using thermocouples. Thermocouples are to consist of 30 AWG wires. Larger size wires may be used, but they shall not exceed 24 AWG and shall not be large enough to result in a heat sink condition on the part under test.
13A.8 During the normal temperature test, temperature measurement T shall not exceed (Tmax + Tamb-Tma)
13B Lithium Polymer Battery Pack Surface Temperature Test
13B.1 A lithium polymer battery pack with enclosure shall be subjected to a normal temperature test under both input (charging) and output (discharging) conditions.
13B.2 For the output loading temperature test, a fully charged lithium polymer battery pack shall be subjected to a constant resistive loading across the output terminals of the pack with the output load current set to just below the operating limit of the discharging protection circuit. Temperatures are monitored until thermal stabilization or until the pack is at its specified endpoint voltage, whichever comes first.
13B.3 The input loading temperature test shall be conducted on a fully discharged battery pack, discharged at a constant current of 0.2C/1 hour to a manufacturer specified discharge endpoint voltage.
13B.4 For the input loading temperature test, a fully discharged sample shall be subjected to a CCCV charging method with the maximum charging voltage not to exceed the manufacturer’s recommended maximum charging voltage limits. During the test, the charging current shall not exceed three times the maximum charge current or the operating limit of the charging protection circuit, whichever is less, during the test. Temperatures are monitored until thermal stabilization or until the pack is at its fully charged state, whichever comes first.
13B.5 Temperatures are considered to be stabilized when three successive readings are taken at intervals of 10 percent of the previously elapsed duration of the test, but not less than 15 minutes, indicate no further increase.
13B.6 Protective devices within the pack shall not operate during the test.
13B.7 Temperatures are monitored on the accessible surfaces of the pack enclosure using thermocouples. Thermocouples are to consist of 30 AWG wires. Larger size wires may be used, but they shall not exceed 24 AWG.
13B.8 During the normal temperature test, temperature measurement T shall not exceed (Tmax + Tamb − Tma)
Lithium Polymer Battery UL2054 Mechanical Test
Crush Test
The component cell has approved by Underwriter Laboratories Inc. according to UL1642.
14.1 The lithium polymer batteries are to be tested in an ambient temperature of 20 ±5°C (68 ±9°F).
14.2 A lithium polymer battery is to be crushed between two flat surfaces. The force for the crushing is to be applied by a hydraulic ram or a similar force mechanism. The flat surfaces are to be brought in contact with the cells and the crushing is to be continued until an applied force of 13 ± 1.0 KN (3000 ± 224 pounds) is reached. Once the maximum force has been obtained, it is to be released.
14.3 A cylindrical or prismatic lithium polymer battery is to be crushed with its longitudinal axis parallel to the flat surfaces of the crushing apparatus. A prismatic lithium polymer battery is also to be rotated 90 degrees around its longitudinal axis so that both the wide and narrow sides will be subjected to the crushing force. Each sample battery is to be subjected to a crushing force in only one direction. Separate samples are to be used for each test.
14.4 A coin or button lithium polymer battery is to be crushed with the flat surface of the lithium polymer battery parallel with the flat surfaces of the crushing apparatus.
14.5 The samples shall not explode or catch fire.
Impact Test
The component cell has approved by Underwriter Laboratories Inc. according to UL1642.
15.1 The lithium polymer batteries are to be tested in an ambient temperature of 20 ±5°C (68 ±9°F).
15.2 A test sample lithium polymer battery is to be placed on a flat surface. A 15.8 mm (518 inches) diameter bar is to be placed across the center of the sample. A 9.1 ±0.46 kg (20 ±1 pound) weight is to be dropped from a height of 610 ±25 mm (24 ±1 inch) onto the sample.
15.3 A cylindrical or prismatic lithium polymer battery is to be impacted with its longitudinal axis parallel to the flat surface and perpendicular to the longitudinal axis of a 15.8 mm (5/8 inch) diameter curved surface lying across the center of the test sample. A prismatic battery is also to be rotated 90 degrees around its longitudinal axis so that both the wide and narrow sides will be subjected to the impact. Each sample lithium polymer battery is to be subjected to only a single impact. Separate samples are to be used for each test.
15.4 A coin or button lithium polymer battery is to be impacted with the fiat surface of the test sample parallel to the flat surface and the 15.8 mm (5/8 inch) diameter curved surface lying across its center.
15.5 The samples shall not explode or catch fire.
Shock Test
The component cell has approved by Underwriter Laboratories Inc. according to UL1642.
16.1 The lipo cell is to be secured to the testing machine by means of a rigid mount that supports all mounting surfaces of the cell. Each cell shall be subjected to a total of three shocks of equal magnitude. The shocks are to be applied in each of three mutually perpendicular directions unless it has only two axes of symmetry in which case only two directions shall be tested. Each shock is to be applied in a direction normal to the face of the cell. For each shock, the cell is to be accelerated in such a manner that during the initial 3 milliseconds the minimum average acceleration is 75 g (where g is the local acceleration due to gravity). The peak acceleration shall be between 125 and 175 g Cells shall be tested at a temperature of 20 ±5°C (68 ±9°F).
16.2 The samples shall not explode or catch fire.
16.3 The sample shall be examined 6 hours after testing and shall not vent or leak as described in 5.2.
Vibration Test
The component cell has approved by Underwriter Laboratories Inc. according to UL1642.
17.1 The lithium polymer batteries are to be tested in an ambient temperature of 20 ±5°C (68 ±9°F).
17.2 A lithium polymer battery is to be subjected to simple harmonic motion with an amplitude of 0.8 mm (0.03 inch) [1.6 mm (0.06 inch) total maximum excursion].
17.3 The frequency is to be varied at the rate of 1 hertz per minute between 10 and 55 hertz and return in not less than 90 nor more than 100 minutes. The battery is to be tested in three mutually perpendicular directions. For a battery that has only two axes of symmetry, the battery is to be tested perpendicular to each axis.
17.4 The samples shall not explode or catch fire.
17.5 The sample shall be examined 6 hours after testing and shall not vent or leak as described in 5.2.
Lithium Polymer Battery UL2054 Enclosure Test
Vibration Test
18.1 The lithium polymer batteries are to be tested in an ambient temperature of 20 ±5°C (68 ±9°F).
18.2 Lithium Polymer Batteries with outer plastic enclosures shall be subjected to the tests described in Sections 19, 20, and 21. Lithium Polymer Batteries with outer enclosures made from materials other than plastic shall be subjected to the tests described in Sections 19 and 21
250 N Steady Force Test
19.1 The lithium polymer batteries are to be tested in an ambient temperature of 20 ±5°C (68 ±9°F).
19.2 External enclosures of the lithium polymer battery pack are to be subjected to a steady force of 250 ±10 N (56 ±2 pounds-force) for a period of 5 seconds, applied in turn to the top, bottom and sides of the battery pack enclosure by means of a suitable test tool providing contact over a circular plane surface 30 mm (1.2 inches) in diameter.
19.3 The samples shall not explode or catch fire. The outer battery enclosure shall not crack to the extent that the cells or any protective devices are exposed. Openings in the enclosure created as a result of application of the 250 N steady force shall meet the criteria of 4.1.5
19.4 The sample shall be examined 6 hours after testing and shall not vent or leak as described in 5.2.
Mold Stress Relief Test
20.1 Each of the three samples is to be placed in a full-draft circulating-air oven maintained at a uniform temperature of 70°C (1 58°F). The samples are to remain in the oven for 7 hours.
Exception: If the maximum temperature, T, recorded on the lithium polymer battery pack thermoplastic enclosure parts, obtained during the normal temperature test of Section 13A exceeds 60°C (140°F), then the oven temperature is to be maintained at a temperature equal to T + 10°C (50°F).
20.2 Deleted effective November 11, 2011
20.2.1 To prevent hazards from overheating energized cells, samples shall either be fully discharged prior to conditioning or provided with ”dummy” cells, which are representative of the actual cells
20.3 After careful removal from the oven and after returning to room temperature following the conditioning described in 20.3, the samples shall show no evidence of mechanical damage that would result in damage to cells or protective circuitry. In addition, the lithium polymer battery enclosures shall not crack, warp, or melt to the extent that the cells or any protective devices are exposed. Openings in the enclosure created as a result of the conditioning shall meet the criteria of 4.1.5
Lithium Polymer Battery UL2054 Fire Exposure Tests
Projectile Test
The component cell has approved by Underwriter Laboratories Inc., according to UL1642.
22.1 When subjected to the test described in 22.2 — 22.5, no part of an exploding cell or battery shall create a hole in the wire screen cage or penetrate the wire screen cage such that some or all of the cell or lithium polymer battery protrudes through the screen cage.
22.2 Each test sample cell or lithium polymer battery is to be placed on a screen that covers a 102 mm (4 inches) diameter hole in the center of a platform table. The screen is to be constructed of a steel wire mesh having 20 openings per inch (25.4 mm) and a wire diameter of 0.43 mm (0.017 inches.
22.3 The screen is to be mounted 38 mm (1-1/2 inch) above a burner. The fuel and airflow rates are to be set to provide a bright blue flame that causes the supporting screen to glow a bright red.
22.4 An eight-sided covered wire cage, 610 mm (2 feet) across, and 305 mm (1 foot) high, made from metal screening, is to be placed over the test sample. See Figure 22.1. The metal screening is to be constructed from 0.25 mm (0.010 inches) diameter aluminum wire with 16— 18 wires per inch (25.4 mm> in each direction.
22.5 The sample is to be heated and shall remain on the screen until it explodes, or the cell or lithium polymer battery has ignited and burned out. It is not required to secure the sample in place unless it is at risk of falling off the screen before the test is completed. When needed, the sample shall be obtained to the screen with a single wire tied around the sample.
Precautions for safe handling
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes, and clothing. Wear personal protective equipment.
Wash thoroughly after handling. Use this material with adequate ventilation.
The product is not explosive.
Lithium Polymer Battery UL2054 Environmental Tests
Heating Test
The component cell has approved by Underwriter Laboratories Inc. according to UL1642.
23.1 The sample shall not explode or catch fire when subjected to the test described in 23.2 — 23.4.
23.2 A lithium polymer battery is to be heated in gravity convection or circulating air oven with an initial temperature of 20 ±5°C (68 ±9° F).
23.3 The temperature of the oven is to be raised at a rate of 5 ±2°C (9 ±3.6° F) per minute to a temperature of 130 ±2°C (266 ±3.6°F) and remain at that temperature for 10 minutes.
23.4 The sample shall return to room temperature (20 ±5°C) and then be examined.
Temperature Cycling Test
The component cell has approved by Underwriter Laboratories Inc. according to UL1642.
24.1 The lithium polymer batteries are to be placed in a test chamber and subjected to the following cycles: a) Raising the chamber-temperature to 70 3°C (158 5°F) within 30 minutes and maintaining this temperature for 4 hours. b) Reducing the chamber temperature to 203°C (68 5°F) within 30 minutes and maintaining this temperature for 2 hours. c) Reducing the chamber temperature to minus 40 3°C (minus 40 5°F) within 30 minutes and maintaining this temperature for 4 hours. d) Raising the chamber temperature to 20 3°C (68 5°F) within 30 minutes. e) Repeating the sequence for a further 9 cycles. f) After the 10th cycle, storing the batteries for a minimum of 24 hours at 205°C (689°F) prior to examination
24.2 The samples shall not explode or catch fire. In addition, the samples shall not vent or leak as described in 5.2.
Lithium Polymer Battery UL2054 Marking
General
25.1 A lithium polymer battery shall be legibly and permanently marked with:
a) The manufacturer’s name, trade name, or trademark or another descriptive marking by which the organization responsible for the product may be identified;
b) A distinctive number or the equivalent;
c) The electrical rating in Vdc and Ah. (Secondary lithium polymer batteries may be marked in Wh rather than Ah); and
d) The date or other dating period of manufacture not exceeding any three consecutive months Exception No. 1: The manufacturer’s identification may be in a traceable code if the product is identified by the brand or trademark owned by a private labeler Exception No. 2: The date of manufacture may be abbreviated or maybe in a nationally accepted conventional code or in a code affirmed by the manufacturer, provided that the code: a) Does not repeat in less than 10 years, and b) Does not require reference to the production records of the manufacturer to determine when the product was manufactured.
25.2 When a manufacturer produces the lithium polymer battery at more than one factory, each battery shall have a distinctive marking to identify it as the product of a particular factory.
25.3 A lithium polymer battery or the smallest unit package or instructions provided with each battery shall include the following statements or equivalent:
a) An attention word, such as ―Caution‖,
‖Warning‖ , or ―Danger‖
b) A brief description of possible hazards associated with the mishandling of the lithium polymer battery, such as burn hazard, fire hazard, an explosion hazard.
c) A list of actions to take to avoid possible hazards, such as do not crush, disassemble, dispose of in fire, or similar actions, and for primary batteries, do not charge.
d) Instructions regarding replacement lithium polymer batteries if the lithium polymer batteries are replaceable by the user
Statements or Equivalent
25.3.1 A lithium polymer battery pack shall be marked with the following or equivalent: ―CAUTION: Risk of Fire and Burns. Do Not Open, Crush, Heat Above
(manufacturer’s specified maximum temperature) or Incinerate. Follow Manufacturer’s Instructions‖ This wording or equivalent shall also be included in the instructions packaged with the battery pack
Exception No. 1: A lithium polymer battery pack not provided with an enclosure, need not be marked but shall include the above wording or equivalent in the instructions provided with the pack
Exception No. 2: If space does not permit marking on the battery, the marking may be on the smallest unit package.
25.4 The manufacturer’s specified charging instructions shall be included for secondary batteries. Primary batteries shall include instructions indicating that the lithium polymer batteries shall not be charged
25.5 A cell or lithium polymer battery that is less than 32 mm (1.25 inches) in diameter by 3.8 mm (0.15 in) thick shall include the following marking or equivalent on the smallest unit package or instructions provided with each cell or battery:
“Caution — Never put batteries in mouth. If swallowed, contact your physician or local poison control center.”
25.6 Batteries which meet the requirements of the Limited Power Source Test, Paragraph 13.4, may include the Marking ―” Limited Power Source‖ or ―LPS”